Chavan, Subhash P., Sharma, Pallavi, Sivappa, Rasapalli , Bhadbhade, Mohan B., Gonnade, Rajesh G. and Kalkote, Uttam R. (2003) Enantioselective synthesis of L-CCG-I. Journal of the American Chemical Society, 68 (17). pp. 6871-6819. ISSN 0002-7863
Full content URL: http://pubs.acs.org/doi/pdf/10.1021/jo0345188
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| Item Type: | Article |
|---|---|
| Item Status: | Live Archive |
Abstract
Introduction of natural menthol as the chiral
auxiliary in a ç-Br-R,â-unsaturated ester leads to enantioselective generation of three chiral centers in a single step
on reaction with a glycine anion equivalent to provide
L-CCG-I in 94% ee.
| Additional Information: | Introduction of natural menthol as the chiral auxiliary in a ç-Br-R,â-unsaturated ester leads to enantioselective generation of three chiral centers in a single step on reaction with a glycine anion equivalent to provide L-CCG-I in 94% ee. |
|---|---|
| Keywords: | amino acid, MIRC, cyclopropane, CCG |
| Subjects: | F Physical Sciences > F160 Organic Chemistry |
| Divisions: | College of Science > School of Life Sciences |
| ID Code: | 7117 |
| Deposited On: | 23 Dec 2012 22:12 |
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