Sharma, Pallavi, Griffiths, Nicholas and Moses, John E. (2008) Biomimetic synthesis and structural revision of tridachiahydropyrone. Organic Letters, 10 (18). pp. 4025-4027. ISSN 1523-7060
Full content URL: http://pubs.acs.org/doi/pdf/10.1021/ol8015836
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
A short synthesis of the revised structure of the marine natural product tridachiahydropyrone is described. A novel biomimetic photochemical
electrocyclization was employed to construct the bicyclic carbon framework from an open-chain polyene precursor. The spectroscopic data
matched that of the isolated natural product, supporting a revised structure of this complex metabolite.
| Additional Information: | A short synthesis of the revised structure of the marine natural product tridachiahydropyrone is described. A novel biomimetic photochemical electrocyclization was employed to construct the bicyclic carbon framework from an open-chain polyene precursor. The spectroscopic data matched that of the isolated natural product, supporting a revised structure of this complex metabolite. |
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| Keywords: | biomimetic synthesis, polypropionate, electrocyclisation, mollusc |
| Subjects: | F Physical Sciences > F160 Organic Chemistry |
| Divisions: | College of Science > School of Life Sciences |
| ID Code: | 7112 |
| Deposited On: | 24 Dec 2012 22:19 |
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