Zhu, Z., Wang, Z., Jian, Y. , Sun, H., Zhang, G., Lynam, J.M., McElroy, Con, Burden, T.J., Inight, R.L., Fairlamb, I.J.S., Zhang, W. and Gao, Z. (2021) Pd-Catalysed carbonylative Suzuki–Miyaura cross-couplings using Fe(CO) 5 under mild conditions: generation of a highly active, recyclable and scalable ‘Pd–Fe’ nanocatalyst. Green Chemistry, 23 (2). pp. 920-926. ISSN 1463-9262
Full content URL: https://doi.org/10.1039/d0gc03036h
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
The dual function and role of iron(0) pentacarbonyl Fe(CO)5 has been identified in gaseous CO-free carbonylative Suzuki-Miyaura cross-couplings, in which Fe(CO)5supplied COin situ, leading to the propagation of catalytically active Pd-Fe nanoparticles. Compared with typical carbonylative reaction conditions, CO gas (at high pressures), specialised exogenous ligands and inert reaction conditions were avoided. Our developed reaction conditions are mild, do not require specialised CO high pressure equipment, and exhibit wide functional group tolerance, giving a library of biaryl ketones in good yields.
| Additional Information: | cited By 6 |
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| Keywords: | palladium, Suzuki-Miyaura coupling |
| Subjects: | F Physical Sciences > F100 Chemistry |
| Divisions: | College of Science > School of Chemistry |
| Related URLs: | |
| ID Code: | 54737 |
| Deposited On: | 30 May 2023 13:53 |
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