Nash, Toby J. and Pattison, Graham (2015) Apparent Electrophilic Fluorination of 1,3-Dicarbonyl Compounds Using Nucleophilic Fluoride Mediated by PhI(OAc)2. European Journal of Organic Chemistry, 2015 (17). pp. 3779-3786. ISSN 1434-193X
Full content URL: https://doi.org/10.1002/ejoc.201500370
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GPToby Electrophilic Fluorination PhIF2 EuroJOC Final Corrected Version.doc - Whole Document Restricted to Repository staff only 1MB |
| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
The apparent electrophilic fluorination of 1,3-dicarbonyl compounds using Et3N·3HF mediated by the in-situ formation of PhIF2 from PhI(OAc)2 is reported. This can be performed safely in standard laboratory glassware, and this approach may reduce our reliance on difficult-to-handle fluorine gas and expensive electrophilic fluorinating agents derived from elemental fluorine.
| Keywords: | fluorination, hypervalent iodine, 1-3-dicarbonyl |
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| Subjects: | F Physical Sciences > F100 Chemistry |
| Divisions: | College of Science > School of Chemistry |
| ID Code: | 52247 |
| Deposited On: | 31 Oct 2022 14:11 |
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