Britovsek, G.J.P., England, Jason, Spitzmesser, S.K. , White, A.J.P. and Williams, D.J. (2005) Synthesis of iron(II), manganese(II), cobalt(II) and ruthenium(II) complexes containing tridentate nitrogen ligands and their application in the catalytic oxidation of alkanes. Dalton Transactions, 5 . pp. 945-955. ISSN 1477-9226
Full content URL: https://doi.org/10.1039/B414813D
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
A series of Fe(II), Mn(II), Co(II) and Ru(II) complexes containing bis(imino)pyridine or bis(amino)pyridine ligands and weakly coordinating triflate (OTf−) or non-coordinating SbF6− anions have been prepared. The complexes have been fully characterized including several solid-state structure analyses. Two unusual mono-chelate six-coordinate bis(imino)pyridine Fe(II) and Mn(II) complexes have been observed. The catalytic properties of the complexes for the oxidation of cyclohexane with H2O2 have been evaluated. Only the Fe(II) complexes have shown catalytic activity, which is mainly due to Fenton-type free radical auto-oxidation.
| Additional Information: | cited By 88 |
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| Keywords: | Catalysis, Cobalt compounds, Hydrocarbons, Iron compounds, Magnesium compounds, Nuclear magnetic resonance, Organometallics, Oxidation, Paraffins, Ruthenium compounds, Thermodynamics, Catalytic oxidation, Iron-based catalysts, Ligands, Radical cations, Synthesis (chemical) |
| Subjects: | F Physical Sciences > F120 Inorganic Chemistry F Physical Sciences > F110 Applied Chemistry |
| Divisions: | College of Science > School of Chemistry |
| ID Code: | 51940 |
| Deposited On: | 19 Oct 2022 10:59 |
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