Ray, K., England, Jason, Fiedler, A.T. , Martinho, M., Münck, E. and Que Jr., L. (2008) An Inverted and More Oxidizing Isomer of [FeIV(O)(tmc)(NCCH3)]2+. Angewandte Chemie International Edition, 47 (42). pp. 8068-8071. ISSN 1433-7851
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
Oxoferryl gymnastics: The oxo and CH3CN ligands in 1-NCCH3 can swap positions in the presence of iodosobenzene and tetrafluoroborate anion leading to the generation of a more reactive isomer 2. This conversion is proposed to take place via an activated FeIV unit (1 a) or a transient dioxoiron(VI) species (1 b).
| Keywords: | Biochemistry, Chemical reactions, Coordination reactions, Isomers, Bioinorganic chemistry, Coordination modes, Cyclam, High-valent compounds, Nonheme iron complexes, Iron compounds, divalent cation, iron, organometallic compound, oxygen, article, chemical structure, chemistry, isomerism, nuclear magnetic resonance spectroscopy, spectrophotometry, Cations, Divalent, Magnetic Resonance Spectroscopy, Molecular Structure, Organometallic Compounds, Oxygen, Spectrophotometry |
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| Subjects: | F Physical Sciences > F120 Inorganic Chemistry |
| Divisions: | College of Science > School of Chemistry |
| ID Code: | 51930 |
| Deposited On: | 18 Oct 2022 15:49 |
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