An Inverted and More Oxidizing Isomer of [FeIV(O)(tmc)(NCCH3)]2+

Ray, K., England, Jason, Fiedler, A.T. , Martinho, M., Münck, E. and Que Jr., L. (2008) An Inverted and More Oxidizing Isomer of [FeIV(O)(tmc)(NCCH3)]2+. Angewandte Chemie International Edition, 47 (42). pp. 8068-8071. ISSN 1433-7851

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Item Type:Article
Item Status:Live Archive

Abstract

Oxoferryl gymnastics: The oxo and CH3CN ligands in 1-NCCH3 can swap positions in the presence of iodosobenzene and tetrafluoroborate anion leading to the generation of a more reactive isomer 2. This conversion is proposed to take place via an activated FeIV unit (1 a) or a transient dioxoiron(VI) species (1 b).

Keywords:Biochemistry, Chemical reactions, Coordination reactions, Isomers, Bioinorganic chemistry, Coordination modes, Cyclam, High-valent compounds, Nonheme iron complexes, Iron compounds, divalent cation, iron, organometallic compound, oxygen, article, chemical structure, chemistry, isomerism, nuclear magnetic resonance spectroscopy, spectrophotometry, Cations, Divalent, Magnetic Resonance Spectroscopy, Molecular Structure, Organometallic Compounds, Oxygen, Spectrophotometry
Subjects:F Physical Sciences > F120 Inorganic Chemistry
Divisions:College of Science > School of Chemistry
ID Code:51930
Deposited On:18 Oct 2022 15:49

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