England, Jason, Guo, Y., Van Heuvelen, K.M. , Cranswick, M.A., Rohde, G.T., Bominaar, E.L., Münck, E. and Que Jr., L. (2011) A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site. Journal of the American Chemical Society, 133 (31). pp. 11880-11883. ISSN 0002-7863
Full content URL: https://doi.org/10.1021/ja2040909
Full text not available from this repository.
| Item Type: | Article |
|---|---|
| Item Status: | Live Archive |
Abstract
The trigonal-bipyramidal high-spin (S = 2) oxoiron(IV) complex [FeIV(O)(TMG2dien)(CH3CN)]2+ (7) was synthesized and spectroscopically characterized. Substitution of the CH3CN ligand by anions, demonstrated here for X = N3– and Cl–, yielded additional S = 2 oxoiron(IV) complexes of general formulation [FeIV(O)(TMG2dien)(X)]+ (7-X). The reduced steric bulk of 7 relative to the published S = 2 complex [FeIV(O)(TMG3tren)]2+ (2) was reflected by enhanced rates of intermolecular substrate oxidation.
| Keywords: | CN-ligand, Oxoiron, Steric bulk, Substrate oxidation, Chlorine compounds, anion, hydrogen, iron complex, methyl group, unclassified drug, article, density functional theory, oxidation, spectroscopy, synthesis, Coordination Complexes, Ferrous Compounds, Molecular Structure, Quantum Theory |
|---|---|
| Subjects: | F Physical Sciences > F120 Inorganic Chemistry |
| Divisions: | College of Science > School of Chemistry |
| ID Code: | 51922 |
| Deposited On: | 14 Oct 2022 10:27 |
Repository Staff Only: item control page