Constanzo, A, Poggi, A, Looijmans, S , Venkatraman, D, Sawyer, D, Puskar, L, McIlroy, Claire and Cavallo, D (2022) The role of molar mass in achieving isotropy and interlayer strength in Mat-Ex printed polylactic acid. Polymers, 14 (14). p. 2792. ISSN 2073-4360
Full content URL: https://doi.org/10.3390/polym14142792
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polymers-14-02792.pdf - Whole Document Available under License Creative Commons Attribution 4.0 International. 3MB |
Item Type: | Article |
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Item Status: | Live Archive |
Abstract
There has been extensive research in the field of material-extrusion (Mat-Ex) 3D printing to improve the inter-layer bonding process. Much research focusses on how various printing conditions may be detrimental to weld strength; many different feedstocks have been investigated along with various additives to improve strength. Surprisingly, there has been little attention directed toward how fundamental molecular properties of the feedstock, in particular the average molar mass of the polymer, may contribute to microstructure of the weld. Here we showed that weld strength increases with decreasing average molar mass, contrary to common observations in specimens processed in more traditional ways, e.g., by compression molding. Using a combination of synchrotron infra-red polarisation modulation microspectroscopy measurements and continuum modelling, we demonstrated how residual molecular anisotropy in the weld region leads to poor strength and how it can be eradicated by decreasing the relaxation time of the polymer. This is achieved more effectively by reducing the molar mass than by the usual approach of attempting to govern the temperature in this hard to control non-isothermal process. Thus, we propose that molar mass of the polymer feedstock should be considered as a key control parameter for achieving high weld strength in Mat-Ex.
Keywords: | Material Extrusion, Weld strength, Constitutive Modelling |
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Subjects: | F Physical Sciences > F200 Materials Science H Engineering > H142 Solid Mechanics H Engineering > H990 Engineering not elsewhere classified H Engineering > H141 Fluid Mechanics G Mathematical and Computer Sciences > G120 Applied Mathematics |
Divisions: | College of Science > School of Mathematics and Physics |
ID Code: | 51687 |
Deposited On: | 13 Sep 2022 10:26 |
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