Colston, B. J. and Choppin, G. R. (2001) Evaluating the performance of a stopped-flow near-infrared spectrophotometer for studying fast kinetics of actinide reactions. Journal of Radioanalytical and Nuclear Chemistry, 250 (1). pp. 21-26. ISSN 0236-5731
Full content URL: http://dx.doi.org/10.1023/A:1013251827451
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
A stopped-flow rapid mixing device interfaced to a high performance miniature fibre optic CCD NIR detector permits the study of fast redox kinetics of actinide reactions at minimal cost. The use of fibre optics enables the stopped-flow device to be readily used in a glove-box. The system has been evaluated at 980 nm by observing the in-growth of Np(V) from a fast reduction reaction of Np(VI), and has been shown to perform well in this spectral region.
| Additional Information: | A stopped-flow rapid mixing device interfaced to a high performance miniature fibre optic CCD NIR detector permits the study of fast redox kinetics of actinide reactions at minimal cost. The use of fibre optics enables the stopped-flow device to be readily used in a glove-box. The system has been evaluated at 980 nm by observing the in-growth of Np(V) from a fast reduction reaction of Np(VI), and has been shown to perform well in this spectral region. |
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| Keywords: | Fast kinetic reactions, Neptunium reduction, Stopped-flow spectrophotometry, Fibre optics |
| Subjects: | F Physical Sciences > F180 Analytical Chemistry |
| Divisions: | College of Science > School of Life Sciences |
| ID Code: | 5123 |
| Deposited On: | 29 Apr 2012 13:34 |
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