Roy, Souvik, Bhunia, Asamanjoy, Schuth, Nils , Haumann, Michael and Ott, Sascha (2018) Light-driven hydrogen evolution catalyzed by a cobaloxime catalyst incorporated in a MIL-101(Cr) metal–organic framework. Sustainable Energy & Fuels, 2 (6). pp. 1148-1152. ISSN 2398-4902
Full content URL: https://doi.org/10.1039/c8se00072g
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| Item Type: | Article |
|---|---|
| Item Status: | Live Archive |
Abstract
A cobaloxime H2 evolution catalyst with a hydroxo-functionalized pyridine ligand, Co(dmgH)2(4-HEP)Cl [dmgH = dimethylglyoxime, 4-HEP = 4-(2-hydroxyethyl)pyridine] was immobilized on a chromium terephthalate metal–organic framework (MOF), MIL-101(Cr), to construct a MOF-catalyst hybrid which displays good photocatalytic H2 evolution activity. The longevity of the cobaloxime catalyst is increased by MOF incorporation, but limited by the stability of the cobalt–pyridine bond under turnover conditions.
| Keywords: | Metal–organic framework (MOF), Ligands, Catalysis |
|---|---|
| Subjects: | F Physical Sciences > F100 Chemistry F Physical Sciences > F161 Organometallic Chemistry |
| Divisions: | College of Science > School of Chemistry |
| ID Code: | 40666 |
| Deposited On: | 17 Apr 2020 12:17 |
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