Targetable Mechanical Properties by Switching between Self-Sorting and Co-assembly with In Situ Formed Tripodal Ketoenamine Supramolecular Hydrogels

Foster, Jamie S., Prentice, Andrew W., Forgan, Ross S. , Paterson, Martin J. and Lloyd, Gareth O. (2018) Targetable Mechanical Properties by Switching between Self-Sorting and Co-assembly with In Situ Formed Tripodal Ketoenamine Supramolecular Hydrogels. ChemNanoMat, 4 (8). pp. 853-859. ISSN 2199-692X

Full content URL: http://doi.org/10.1002/cnma.201800198

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Targetable Mechanical Properties by Switching between Self-Sorting and Co-assembly with In Situ Formed Tripodal Ketoenamine Supramolecular Hydrogels
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Abstract

A new family of supramolecular hydrogelators are introduced in which self-sorting and co-assembly can be utilised in the tuneability of the mechanical properties of the materials, a property closely tied to the nanostructure of the gel network. The in situ reactivity of the components of the gelators allows for system chemistry concepts to be applied to the formation of the gels and shows that molecular properties, and not necessarily the chemical identity, determines some gel properties in these family of gels.

Keywords:supramolecular gel, self-sorting, co-assembly, dynamic covalent chemistry, nanofibers
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
ID Code:38095
Deposited On:15 Apr 2020 09:21

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