Naeem, Ayesha, Ting, Valeska P., Hintermair, Ulrich , Tian, Mi, Telford, Richard, Halim, Saaiba, Nowell, Harriott, Holynska, Malgorzata, Teat, Simon J., Scowen, Ian J. and Nayak, Sanjit (2016) Mixed-linker approach in designing porous zirconium-based metal-organic frameworks with high hydrogen storage capacity. Chemical Communications, 52 (50). pp. 7826-7829. ISSN 1359-7345
Full content URL: https://doi.org/10.1039/c6cc03787a
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__network.uni_staff_S2_jpartridge_c6cc03787a.pdf - Whole Document Available under License Creative Commons Attribution. 2MB |
| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
Three highly porous Zr(IV)-based metal–organic frameworks, UBMOF-8, UBMOF-9, and UBMOF-31, were synthesized by using 2,2′-diamino-4,4′-stilbenedicarboxylic acid, 4,4′-stilbenedicarboxylic acid, and combination of both linkers, respectively. The mixed-linker UBMOF-31 showed excellent hydrogen uptake of 4.9 wt% and high selectivity for adsorption of CO2 over N2 with high thermal stability and moderate water stability with permanent porosity and surface area of 2552 m2 g−1.
| Keywords: | metal-organic frameworks, mixed-linker, Zirconium, hydrogen storage, NotOAChecked |
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| Subjects: | F Physical Sciences > F160 Organic Chemistry F Physical Sciences > F100 Chemistry |
| Divisions: | College of Science > School of Chemistry |
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| ID Code: | 23554 |
| Deposited On: | 25 Jul 2016 08:42 |
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