Pop, R.a, Cui, J.L.b, Adriaenssens, L.a , Comte, V.a and Le Gendre, P.a (2011) Me2C(C5H4)2TiMe2: An open-bent titanocene catalyst for the hydro-silylation of bulky 1,3-dienes. Synlett (5). pp. 679-683. ISSN 09365214
Full content URL: http://www.scopus.com/inward/record.url?eid=2-s2.0...
Full text not available from this repository.
| Item Type: | Article |
|---|---|
| Item Status: | Live Archive |
Abstract
Motivated by our preliminary results on Cp2TiF 2-catalysed 1,4-hydrosilylation of monosubstituted dienes, we assessed the performance of several titanium complexes for the hydrosilylation of 2,3-dimethylbutadiene, a representative bulky diene. An open-bent titanocene complex Me2C(C5H4)2TiMe 2 performed the best and proved to be efficient for the hydrosilylation of a variety of substrates such as disubstituted dienes, activated alkenes, and even an acetylene. © Georg Thieme Verlag Stuttgart - New York.
| Additional Information: | cited By 3 The final published version of this article is available online at: https://www.thieme-connect.de/DOI/DOI?10.1055/s-0030-1259687 © 2018 Georg Thieme Verlag KG |
|---|---|
| Keywords: | 2,3 dimethylbutadiene, alkadiene, alkene derivative, disubstituted diene derivative, titanium derivative, titanocene, titanocene complex, unclassified drug, article, catalysis, chemical analysis, chemical structure, complex formation, hydrosilylation, molecular interaction, reaction time, substitution reaction, synthesis, methadology |
| Subjects: | F Physical Sciences > F100 Chemistry |
| Divisions: | College of Science > School of Chemistry |
| ID Code: | 22740 |
| Deposited On: | 25 Jul 2018 10:36 |
Repository Staff Only: item control page