Aubert, C., Barbazanges, M., Jutand, A. et al, Kyne, S. H., Ollivier, C. and Fensterbank, L.
(2014)
Organometallic catalysis for applications in radical chemistry and asymmetric synthesis.
Pure and Applied Chemistry, 86
(3).
pp. 273-281.
ISSN 0033-4545
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Abstract
Two organometallic catalysis studies are presented. The first one deals with the development of a new catalytic agent based on the mixture of a hydride and an iron salt to trigger efficient radical cyclization processes. In a second line of research, we have shown that the use of chiral anions can outperform chiral ligands in a carbocyclization reaction and a 2 + 2 + 2 cycloaddition.
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