Kyne, S. H. and Schiesser, C.H. (2014) N,S-Dimethyldithiocarbamyl oxalates as precursors for determining kinetic parameters for oxyacyl radicals. Chemical Communications, 50 (81). pp. 12040-12042. ISSN 1359-7345
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
N,S-Dimethyldithiocarbamyl oxalates (e.g.6, 10) are novel, readily prepared precursors to alkyloxyacyl radicals 1 that are more suitable for kinetic studies than existing precursors; 10 has allowed the determination of accurate rate data for the cyclization of the butenyloxyacyl radical 5 (kc = 1.2 X 107 s-1 at 21 °C).
| Keywords: | radical, cyclization, kinetics, NotOAChecked |
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| Subjects: | F Physical Sciences > F160 Organic Chemistry |
| Divisions: | College of Science > School of Chemistry |
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| ID Code: | 17610 |
| Deposited On: | 08 Jun 2015 13:15 |
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