Kobayashi, Shoji, Das, Parthasarathi, Wang, Guang Xing , Mita, Takashi, Lear, Martin J. and Hirama, Masahiro (2002) Diastereoselective additions of ethynyl Grignard reagent to erythrulose derivatives. Chemistry Letters, 31 (3). pp. 300-301. ISSN 0366-7022
Full content URL: http://dx.doi.org/10.1246/cl.2002.300
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
Through systematic changes in reaction conditions and with the use of Ti(OiPr)4, the typical stereochemical outcome of
ethynylmagnesium bromide on α,β-O-isopropylidene-erythrulose derivatives has been reversed with exceptional levels of control.
| Keywords: | Erythrulose, Stereoisomer synthesis, Grignard addition |
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| Subjects: | F Physical Sciences > F160 Organic Chemistry |
| Divisions: | College of Science > School of Chemistry |
| ID Code: | 17125 |
| Deposited On: | 17 Apr 2015 11:42 |
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