Yan, Yaw-Kai, Mingos, D. Michael P., Kurmoo, Mohamedally , Li, Wan-Sheung, Scowen, Ian J., McPartlin, Mary, Coomber, A. Treeve and Friend, Richard H. (1995) Two tetrathiafulvalene salts of a new thiophene-functionalised ferracarborane: electrical conductivity as a function of crystal composition. Journal of the Chemical Society, Chemical Communications (10). pp. 997-998. ISSN 0022-4936
Full content URL: http://dx.doi.org/10.1039/C39950000997
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
Two tetrathiafulvalenium (TTF) salts of the new sandwich complex commo-3{,}3prime or minute]-Fe1-(thiophene-2-yl)-1,2-CBH], TTFFe(CBHCHS) and TTFFe(CBHCHS){,} are synthesized; while the 1 : 1 salt is an insulator{,} the 5 : 2 salt is a semiconductor featuring a conducting superlattice associated with a sublattice that shows ferromagnetic interactions between the ferracarborane complexes; single crystal X-ray studies of the 5 : 2 salt indicate that the electrical conductivity originates from a unique mixed-valence TTF network.
| Additional Information: | Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995 |
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| Keywords: | Chemistry |
| Subjects: | F Physical Sciences > F100 Chemistry |
| Divisions: | College of Science > School of Chemistry |
| ID Code: | 13254 |
| Deposited On: | 19 Mar 2014 19:31 |
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