Macrocyclic helicates: complexes of a 34-membered Schiff-base ligand

Fenton, David E., Matthews, Ray W., McPartlin, Mary , Murphy, Brian P., Scowen, Ian J. and Tasker, Peter A. (1994) Macrocyclic helicates: complexes of a 34-membered Schiff-base ligand. Journal of the Chemical Society, Chemical Communications . pp. 1391-1392. ISSN 0022-4936

Full content URL: http://dx.doi.org/10.1039/C39940001391

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Item Type:Article
Item Status:Live Archive

Abstract

A unique double helical macrocyclic configuration of a new 34-membered Schiff-base macrocycle results from convergence of its two pyridine-2,6-diyldiimine units for meridional coordination of divalent metal ions; X-ray structure analysis establishes the cobalt(), nickel() and zinc() complexes as the first structurally characterised macrocyclic helicates.

Additional Information:Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995
Keywords:Chemistry, Analytical chemistry
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
ID Code:13251
Deposited On:19 Mar 2014 19:32

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