Hellmann, Konrad W., Gade, Lutz H., Scowen, Ian J. and McPartlin, Mary (1996) Aggregation of tripodal thallium(I) amides through weak TlI-TlI interactions. Chemical Communications, 1996 (22). pp. 2515-2516. ISSN 1359-7345
Full content URL: http://dx.doi.org/10.1039/CC9960002515
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
Metal exchange between the lithium amide MeSiSiMe2N-(Li)But3 and TlCl yields the corresponding thallium amide MeSiSiMe2N(Tl)But3 1 which aggregates in the solid through weak attractive Tl�Tl interactions to form infinite molecular chains; competing redox chemistry leads to the dimetallated species HCSiMe2N(Tl)But2SiMe2NHBu t 2 in the analogous metal-exchange process involving the trisilylmethane derivative.
| Keywords: | Metal exchange |
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| Subjects: | F Physical Sciences > F100 Chemistry |
| Divisions: | College of Science > School of Chemistry |
| Related URLs: | |
| ID Code: | 13096 |
| Deposited On: | 19 Mar 2014 19:43 |
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