Synthesis and X-ray structural studies of new spiro-cyclotriphosphazenes

Combes-Chamalet, C., Cristau, H.-J., McPartlin, M. , Plenat, F., Scowen, I. J. and Woodroffe, T. M. (1997) Synthesis and X-ray structural studies of new spiro-cyclotriphosphazenes. Journal of the Chemical Society, Perkin Transactions 2 (1). pp. 15-18. ISSN 0300-9580

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The series of four cyclotriphosphazenes containing biphenyl and phenyl groups, N3P3(C12H8)3-nPh 2n, where n = 0-3, (1-4 respectively), has been completed by the synthesis of two new C-bonded spiro-cyclotriphosphazenes, N3P3(C12H8)2Ph 2 2 and N3P3(C12H8)Ph4 3. They have been fully characterised and X-ray structural analysis shows that both compounds have a planar cyclotriphosphazene ring with less overall molecular rigidity compared to the trispirocyclic analogue, 1.

Additional Information:Perkin Transactions 2 ceased publication in 2002. Organic & Biomolecular Chemistry is the RSC's organic chemistry journal for high-quality, original organic chemistry research.
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13093
Deposited On:05 Feb 2014 15:00

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