Freeman, G., Ingham, S. L., Johnson, B. F. G. , McPartlin, M. and Scowen, I. J. (1997) Reaction of [Ru5C(CO)15] and [Ru6C(CO)17] with 1,10-phenanthroline and 2,2'-bipyridyl. Journal of the Chemical Society - Dalton Transactions (15). pp. 2705-2711. ISSN 0300-9246, 1477-9226
Full content URL: http://dx.doi.org/10.1039/A608623C
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
Reaction of the cluster Ru5C(CO)15 1 with the bidentate nitrogen heterocycles 1,10-phenanthroline (phen) and 2,2�-bipyridyl (bipy) in the presence of 1.1 and 2.2 molar equivalents of Me3NO led to a facile metal-metal bond cleavage and a structural change in the cluster to yield the bridged butterfly products Ru5C(CO)14(phen) and Ru5C(CO)14(bipy) respectively as the major products, and the orthometallated derivatives Ru5(μ-H)C(CO)13-(C12H7N 2) and Ru5(μ-H)C(CO)13(C10H7N 2) as the minor product as revealed by spectroscopy and X-ray crystallography.
| Keywords: | Chemistry |
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| Subjects: | F Physical Sciences > F100 Chemistry |
| Divisions: | College of Science > School of Chemistry |
| Related URLs: | |
| ID Code: | 13092 |
| Deposited On: | 19 Mar 2014 17:54 |
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