Schneider, A., Gade, L. H., Breuning, M. , Bringmann, G., Scowen, I. J. and McPartlin, M. (1998) Cooperative reactivity of unsupported early-late heterobimetallics: Ring opening and subsequent decarbonylation of biaryllactones. Organometallics, 17 (9). pp. 1643-1645. ISSN 0276-7333
Full content URL: http://dx.doi.org/10.1021/om980007d
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
Reaction of the heterodinuclear complex HC-{SiMe2N(2-FC6H3)}3Zr-FeC p(CO)2 (1) with 1,3-di-methyl-6H-benzobnaphtho1,2-dpyranone (2) and 1,3-dimethoxy-6H-benzob-naphtho-1,2-dpyranone (3) led to immediate ring opening of the lactones to yield products which combine the biaryl fragment with aryloxyzirconium and acyl-FeCp(CO)2 units. The latter slowly decarbonylate to yield the corresponding heterobimetallic complexes in which the {MCp(CO)2} fragment is directly bonded to the naphthalene ring.
| Additional Information: | Publication Date (Web): April 09, 1998 (Communication) |
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| Keywords: | Chemistry |
| Subjects: | F Physical Sciences > F100 Chemistry |
| Divisions: | College of Science > School of Chemistry |
| Related URLs: | |
| ID Code: | 13076 |
| Deposited On: | 19 Mar 2014 19:11 |
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