Hellmann, K. W., Galka, C. H., Rudenauer, I. , Gade, L. H., Scowen, I. J. and McPartlin, M. (1998) Metal-ligand versus metal-metal redox chemistry: thallium(I)-induced synthesis of 4,9-diaminoperylenequinone-3,10-diimine derivatives. Angewandte Chemie - International Edition, 37 (13-14). pp. 1948-1952. ISSN 1433-7851
Full content URL: http://dx.doi.org/10.1002/(SICI)1521-3773(19980803...
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
The choice of the metal determines the redox chemical degradation of monovalent Group 13 metal amides containing a 1,8-diaminonaphthalene derivative as a difunctional amido ligand. Compound 1 reacts with InCl by a selective disproportionation to yield a dinuclear In(II)-In(II) complex (the In-In bond length of 2.7237(6) Ã is the shortest measured so far). In contrast, the intramolecular redox reaction of 1 with TlCl leads to the oxidative coupling of two naphthalene units to generate the tetra-N-functionalized perylene derivative 2.
| Additional Information: | Article first published online: 17 DEC 1998 |
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| Keywords: | Dyes, Indium, Mixed-valent compounds, Redox chemistry, Thallium |
| Subjects: | F Physical Sciences > F100 Chemistry |
| Divisions: | College of Science > School of Chemistry |
| Related URLs: | |
| ID Code: | 13074 |
| Deposited On: | 19 Mar 2014 17:49 |
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