Beynek, Nesrin, McPartlin, Mary, Murphy, Brian P. and Scowen, Ian J. (1998) Ligand control of molecular helicity in the coordination of toxic heavy metal ions: crystal structure of a monohelical cadmium(II) complex. Polyhedron, 17 (11-12). pp. 2137-2140. ISSN 0277-5387
Full content URL: http://dx.doi.org/10.1016/S0277-5387(97)00472-5
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
The new semi-rigid diimine ligand, OpyNpy2, coordinates the toxic heavy metals ions Cd(II) and Hg(II) in a monohelical fashion, as established, in the former, by X-ray crystallography and, in both, by 1H NMR spectroscopy; ligand control is attributed to the helical topology of these complexes of stereochemically non-demanding ions. © 1998 Elsevier Science Ltd. All rights reserved.
| Keywords: | Ligand, Monohelical, Cadmium (II) complex |
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| Subjects: | F Physical Sciences > F100 Chemistry |
| Divisions: | College of Science > School of Chemistry |
| Related URLs: | |
| ID Code: | 13071 |
| Deposited On: | 19 Mar 2014 17:50 |
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