Schubart, Martin, Mitchell, Gemma, Kottke, Thomas , Gade, Lutz H., Scowen, Ian J. and McPartlin, Mary (1999) Ionic cleavage of Ti-Co and Zr-Co bonds: the role of the nucleophilicity of the late transition metal in the reactive behaviour of early-late heterobimetallics. Chemical Communications (3). pp. 233-234. ISSN 1359-7345
Full content URL: http://dx.doi.org/10.1039/A808498J
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
The ionic cleavage of Ti-Co and Zr-Co bonds occurs upon reaction with Bu(t)NC and the products MeSi{SiMe2N(p-Tol)}3Ti(CNBu(t))2lCo(CO)4] 3 and MeSi{SiMe2N(p-Tol)}3Zr(CNBu(t))3Co(CO)4 4 were characterized by single crystal X-ray diffraction; the importance of the nucleophilicity of the late transition metal fragment in reactions of the unsupported early-late heterobimetallics is demonstrated.
| Keywords: | cobalt, titanium, zirconium, article, chemical bond |
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| Subjects: | F Physical Sciences > F100 Chemistry |
| Divisions: | College of Science > School of Chemistry |
| Related URLs: | |
| ID Code: | 13068 |
| Deposited On: | 19 Mar 2014 19:40 |
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