Fabre, Sylvie, Findeis, Bernd, Trosch, Dominique J. M. , Gade, LutzH., Scowen, Ian J. and McPartlin, Mary (1999) Atom-transfer within the coordination sphere of early-late heterobimetallic complexes: rapid deoxygenation of sulfoxides at low temperatures. Chemical Communications (7). pp. 577-578. ISSN 1359-7345
Full content URL: http://dx.doi.org/10.1039/A900010K
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
Extremely rapid oxygen transfer from sulfoxides to a carbonyl ligand to give the corresponding thioether and coordinated CO2 is observed in the reactions of unsupported Zr-Ru heterodimetallic complexes with sulfoxides; this is interpreted to arise from the cooperative reactivity of the two complementary metal complex fragments bound to each other through a highly polar metal-metal bond.
| Keywords: | carbon dioxide, carbonyl derivative, metal complex, oxygen, rubidium, sulfide, sulfoxide, zirconium derivative, article, atom, chemical bond, chemical reaction, chemical structure, low temperature |
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| Subjects: | F Physical Sciences > F100 Chemistry |
| Divisions: | College of Science > School of Chemistry |
| Related URLs: | |
| ID Code: | 13067 |
| Deposited On: | 19 Mar 2014 19:34 |
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