Bashall, A., Collier, P. E., Gade, L. H. , McPartlin, M., Mountford, P., Pugh, S. M., Radojevic, S., Schubart, M., Scowen, I. J. and Trosch, D. J. M. (2000) C-C and C-N coupling reactions of an imidotitanium complex with isocyanides. Organometallics, 19 (23). pp. 4784-4794. ISSN 0276-7333
Full content URL: http://dx.doi.org/10.1021/om0005710
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| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
Reaction of the imidotitanium complex (k3-N2Npy)Ti(=NtBu)(py) (1) N2Npy = (2-C5H4N)C(Me)(CH2NSiMe3) 2 with 2,6-xylylisocyanide led to double insertion of the isocyanide into the imidotitanium bond and yielded the four-membered titanacycle (k3-N2Npy)Ti-{N(tBu)C(=N-2,6-Me2C 6H3)C(=N-2,6-C6H3Me2)} (2), which was characterized by X-ray crystallography. © 2000 American Chemical Society.
| Additional Information: | Publication Date (Web): October 21, 2000 |
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| Keywords: | Chemistry |
| Subjects: | F Physical Sciences > F100 Chemistry |
| Divisions: | College of Science > School of Chemistry |
| Related URLs: | |
| ID Code: | 13061 |
| Deposited On: | 19 Mar 2014 19:11 |
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