Enantioselective synthesis of L-CCG-I

Chavan, Subhash P., Sharma, Pallavi, Sivappa, Rasapalli, Bhadbhade, Mohan B., Gonnade, Rajesh G. and Kalkote, Uttam R. (2003) Enantioselective synthesis of L-CCG-I. Journal of the American Chemical Society, 68 (17). pp. 6871-6819. ISSN 0002-7863

Full content URL: http://pubs.acs.org/doi/pdf/10.1021/jo0345188

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Item Type:Article
Item Status:Live Archive

Abstract

Introduction of natural menthol as the chiral
auxiliary in a ç-Br-R,â-unsaturated ester leads to enantioselective generation of three chiral centers in a single step
on reaction with a glycine anion equivalent to provide
L-CCG-I in 94% ee.

Additional Information:Introduction of natural menthol as the chiral auxiliary in a ç-Br-R,â-unsaturated ester leads to enantioselective generation of three chiral centers in a single step on reaction with a glycine anion equivalent to provide L-CCG-I in 94% ee.
Keywords:amino acid, MIRC, cyclopropane, CCG
Subjects:F Physical Sciences > F160 Organic Chemistry
Divisions:College of Science > School of Life Sciences
ID Code:7117
Deposited On:23 Dec 2012 22:12

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