Biomimetic synthesis and structural reassignment of the tridachiahydropyrones

Sharma, Pallavi, Lygo, Barry, Williams, Lewis and Moses, John E. (2009) Biomimetic synthesis and structural reassignment of the tridachiahydropyrones. Journal of the American Chemical Society, 131 (16). pp. 5966-5972. ISSN 0002-7863

Full content URL: http://pubs.acs.org/doi/pdf/10.1021/ja900369z

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Item Type:Article
Item Status:Live Archive

Abstract

The biomimetic synthesis and structural reassignment of tridachiahydropyrone, tridachiahydropyrone B and tridachiahydropyrone C, isolated from mollusks of the order Sacoglossa, using a sequenceof photochemical transformations from a common polyene precursor are described. These complex naturalproducts may act as sunscreens for the producing organism, thus offering protection from harmful UV radiation and oxidative damage

Keywords:biomimetic synthesis, polypropionate, tridachiahydropyrone, photochemical, electrocyclisation
Subjects:F Physical Sciences > F160 Organic Chemistry
Divisions:College of Science > School of Life Sciences
ID Code:7111
Deposited On:23 Dec 2012 21:21

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