Gil-Ramírez, Guzmán, Benet-Buchholz, Jordi, Escudero-Adán, Eduardo C. and Ballester, Pablo (2007) Solid-state self-assembly of a calix[4]pyrrole−resorcinarene hybrid into a hexameric cage. Journal of the American Chemical Society, 129 (13). pp. 3820-3821. ISSN 0002-7863
Full content URL: http://dx.doi.org/10.1021/ja070037k
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Item Type: | Article |
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Item Status: | Live Archive |
Abstract
The solid-state packing of a two-component mixture consisting of the α,α,α,α steroisomer of a calix[4]pyrrole resorcinarene hybrid and tetramethylammonium chloride is controlled by the relative stoichiometry of the mixture in solution. The use of a high molar excess of the ammonium salt induces, in the solid state, a self-assembly process of the calix[4]pyrrole into a supramolecular hexameric structure that corresponds to an octahedron.
Keywords: | Solid-state, Calix4pyrrole, Calix4pyrrole-resorcinarene hybrid, Hexameric cage |
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Subjects: | F Physical Sciences > F100 Chemistry |
Divisions: | College of Science > School of Chemistry |
ID Code: | 22725 |
Deposited On: | 29 Apr 2016 10:56 |
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