Organometallic catalysis for applications in radical chemistry and asymmetric synthesis

Aubert, C., Barbazanges, M., Jutand, A. , Kyne, S. H., Ollivier, C. and Fensterbank, L. (2014) Organometallic catalysis for applications in radical chemistry and asymmetric synthesis. Pure and Applied Chemistry, 86 (3). pp. 273-281. ISSN 0033-4545

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Abstract

Two organometallic catalysis studies are presented. The first one deals with the development of a new catalytic agent based on the mixture of a hydride and an iron salt to trigger efficient radical cyclization processes. In a second line of research, we have shown that the use of chiral anions can outperform chiral ligands in a carbocyclization reaction and a 2 + 2 + 2 cycloaddition.

Keywords:Catalysis, Chirality, Electrochemistry, Hydrides, Iron, Ligands, Organometallics, Homogeneous catalysis, NotOAChecked
Subjects:F Physical Sciences > F161 Organometallic Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:17611
Deposited On:08 Jun 2015 15:28

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