Miao, Ru, Gramani, Subramanian G. and Lear, Martin J. (2009) Stereocontrolled entry to the tricyclo[3.3.0]oxoheptane core of bielschowskysin by a [2+2] cycloaddition of an allene-butenolide. Tetrahedron Letters, 50 (15). pp. 1731-1733. ISSN ISSN
Full content URL: http://dx.doi.org/10.1016/j.tetlet.2009.01.131
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Tetrahedron Lett-2009-1731.pdf - Whole Document Restricted to Repository staff only 272kB |
| Item Type: | Article |
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| Item Status: | Live Archive |
Abstract
As part of ongoing transannulation studies, the practical synthesis of an allene-linked c-butenolide from L-malic acid and its substrate-controlled [2+2] photocycloaddition to the tricyclic core of bielschowskysin (1) are described.
| Keywords: | Total synthesis studies, Bielschowskysin, Cembranes, Cycloaddition |
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| Subjects: | F Physical Sciences > F160 Organic Chemistry |
| Divisions: | College of Science > School of Chemistry |
| ID Code: | 17117 |
| Deposited On: | 16 Apr 2015 12:05 |
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