Formal synthesis of kingianin A based upon a novel electrochemically-induced radical cation Diels–Alder reaction

Moore, Jonathan C., Davies, E. Stephen, Walsh, Darren A. , Sharma, Pallavi and Moses, John E. (2014) Formal synthesis of kingianin A based upon a novel electrochemically-induced radical cation Diels–Alder reaction. Chemical communications, 50 (83). pp. 12523-12525. ISSN 1359-7345

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Formal synthesis of kingianin A based upon a novel electrochemically-induced radical cation Diels–Alder reaction

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Abstract

The application of electrochemical reactions in natural product synthesis has burgeoned in recent years. We herein report a formal synthesis of the complex and dimeric natural product kingianin A, which employs an electrochemically-mediated radical cation Diels–Alder cycloaddition as the key step.

Keywords:Kingianin A, Natural Product, Electrochemistry, Radical Cation, Diels-Alder, NotOAChecked
Subjects:F Physical Sciences > F160 Organic Chemistry
F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:14833
Deposited On:09 Sep 2014 14:27

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