Metabolites of the higher fungi. Part 32. Rosnecatrone, a phytotoxic bicyclo[4.1.0]hept-3-en-2-one from the fungus Rosellinia necatrix Prill

Edwards, Raymond L., Maitland, Derek J., Scowen, Ian J. , De Sousa, Antonio J. T. and Whalley, Anthony J. S. (2001) Metabolites of the higher fungi. Part 32. Rosnecatrone, a phytotoxic bicyclo[4.1.0]hept-3-en-2-one from the fungus Rosellinia necatrix Prill. Journal of the Chemical Society, Perkin Transactions 1 (5). pp. 537-542.

Full content URL: http://dx.doi.org/10.1039/B008195G

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Item Type:Article
Item Status:Live Archive

Abstract

Rosnecatrone 7 is a phytotoxic metabolite isolated from cultures of a virulent strain of the fungus Rosellinia necatrix. The compound is identified as 5-hydroxy-4-hydroxymethyl-1-(1-hydroxy-3-methylbut-2-enyl)-3-(E )-propenyl-7-oxabicyclo4.1.0hept-3-en-2-one by chemical and physical methods. The absolute configuration is determined and the X-ray structure of its borohydride reduced derivative{,} rosnecatrol 10 as the tetra-acetate is described.

Additional Information:First published online 08 Feb 2001 Perkin Transactions 1 ceased publication in 2002. Organic & Biomolecular Chemistry is the RSC's journal for high-quality, original organic chemistry research
Keywords:Chemistry
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
ID Code:13270
Deposited On:19 Mar 2014 19:31

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