Partial hydrolysis of a Schiff-base tripodal ligand induced by copper(II) salts: crystal structure of the product from reaction with copper(II) perchlorate

Fenton, D. E., Westwood, G. P., Bashall, A. , McPartlin, M. and Scowen, I. J. (1994) Partial hydrolysis of a Schiff-base tripodal ligand induced by copper(II) salts: crystal structure of the product from reaction with copper(II) perchlorate. Journal of the Chemical Society, Dalton Transactions (14). pp. 2213-2214. ISSN 1472-7773

Full content URL: http://dx.doi.org/10.1039/DT9940002213

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Item Type:Article
Item Status:Live Archive

Abstract

The reaction of Cu(ClO4)2 or Cu(NO3)2 with a potentially heptadentate Schiff-base tripod derived from tris(2-aminoethyl)amine and 2-hydroxyacetophenone occurs with accompanying hydrolysis of the ligand; single-crystal X-ray structure analysis of the product involving Cu(ClO4)2 shows the ligand to exist in a zwitterionic form and provide a near square-planar environment for the copper(II) cation.

Keywords:Crystal structure
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13117
Deposited On:19 Mar 2014 19:50

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