Titanium and zirconium complexes containing a novel dianionic trifunctional amido ligand

Friedrich, S., Schubart, M., Gade, L. H., Scowen, I. J., Edwards, A. J. and McPartlin, M. (1997) Titanium and zirconium complexes containing a novel dianionic trifunctional amido ligand. Chemische Berichte, 130 (12). pp. 1751-1759. ISSN 0009-2940

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Item Type:Article
Item Status:Live Archive

Abstract

The novel tridentate diamidoamine ligands RC(2-C5H4N)(CH2NSiMe3) 22- (R = H, CH3) have been synthesized and coordinated to TiIV and ZrIV giving the pentacoordinate complexes MX2(RC(2-C5H4N)(CH2NSiMe 3)2 (M = Ti, Zr; X = Cl, Br). The crystal structure analysis of TiBr2(HC(2-C5H4N)(CH2NSiMe 3)

Additional Information:European Journal of Inorganic Chemistry
Keywords:Amido complexes, Titanium, Zirconium, Alkylmetal compounds
Subjects:F Physical Sciences > F120 Inorganic Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13090
Deposited On:18 Aug 2015 13:55

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