Biomimetic synthesis and structural revision of tridachiahydropyrone

Sharma, Pallavi and Griffiths, Nicholas and Moses, John E. (2008) Biomimetic synthesis and structural revision of tridachiahydropyrone. Organic Letters, 10 (18). pp. 4025-4027. ISSN 1523-7060

Full content URL: http://pubs.acs.org/doi/pdf/10.1021/ol8015836

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Item Type:Article
Item Status:Live Archive

Abstract

A short synthesis of the revised structure of the marine natural product tridachiahydropyrone is described. A novel biomimetic photochemical
electrocyclization was employed to construct the bicyclic carbon framework from an open-chain polyene precursor. The spectroscopic data
matched that of the isolated natural product, supporting a revised structure of this complex metabolite.

Additional Information:A short synthesis of the revised structure of the marine natural product tridachiahydropyrone is described. A novel biomimetic photochemical electrocyclization was employed to construct the bicyclic carbon framework from an open-chain polyene precursor. The spectroscopic data matched that of the isolated natural product, supporting a revised structure of this complex metabolite.
Keywords:biomimetic synthesis, polypropionate, electrocyclisation, mollusc
Subjects:F Physical Sciences > F160 Organic Chemistry
Divisions:College of Science > School of Life Sciences
ID Code:7112
Deposited On:24 Dec 2012 22:19

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