Me2C(C5H4)2TiMe2: An open-bent titanocene catalyst for the hydro-silylation of bulky 1,3-dienes

Pop, R.a and Cui, J.L.b and Adriaenssens, L.a and Comte, V.a and Le Gendre, P.a (2011) Me2C(C5H4)2TiMe2: An open-bent titanocene catalyst for the hydro-silylation of bulky 1,3-dienes. Synlett (5). pp. 679-683. ISSN 09365214

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Item Type:Article
Item Status:Live Archive

Abstract

Motivated by our preliminary results on Cp2TiF 2-catalysed 1,4-hydrosilylation of monosubstituted dienes, we assessed the performance of several titanium complexes for the hydrosilylation of 2,3-dimethylbutadiene, a representative bulky diene. An open-bent titanocene complex Me2C(C5H4)2TiMe 2 performed the best and proved to be efficient for the hydrosilylation of a variety of substrates such as disubstituted dienes, activated alkenes, and even an acetylene. © Georg Thieme Verlag Stuttgart - New York.

Additional Information:cited By 3 The final published version of this article is available online at: https://www.thieme-connect.de/DOI/DOI?10.1055/s-0030-1259687 © 2018 Georg Thieme Verlag KG
Keywords:2,3 dimethylbutadiene, alkadiene, alkene derivative, disubstituted diene derivative, titanium derivative, titanocene, titanocene complex, unclassified drug, article, catalysis, chemical analysis, chemical structure, complex formation, hydrosilylation, molecular interaction, reaction time, substitution reaction, synthesis, methadology
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
ID Code:22740
Deposited On:25 Jul 2018 10:36

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