Solid-state self-assembly of a calix[4]pyrrole−resorcinarene hybrid into a hexameric cage

Gil-Ramírez, Guzmán and Benet-Buchholz, Jordi and Escudero-Adán, Eduardo C. and Ballester, Pablo (2007) Solid-state self-assembly of a calix[4]pyrrole−resorcinarene hybrid into a hexameric cage. Journal of the American Chemical Society, 129 (13). pp. 3820-3821. ISSN 0002-7863

Full content URL: http://dx.doi.org/10.1021/ja070037k

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Abstract

The solid-state packing of a two-component mixture consisting of the α,α,α,α steroisomer of a calix[4]pyrrole resorcinarene hybrid and tetramethylammonium chloride is controlled by the relative stoichiometry of the mixture in solution. The use of a high molar excess of the ammonium salt induces, in the solid state, a self-assembly process of the calix[4]pyrrole into a supramolecular hexameric structure that corresponds to an octahedron.

Keywords:Solid-state, Calix4pyrrole, Calix4pyrrole-resorcinarene hybrid, Hexameric cage
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
ID Code:22725
Deposited On:29 Apr 2016 10:56

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