Quantitative evaluation of anion–π Interactions in solution

Gil-Ramírez, Guzmán and Escudero-Adán, Eduardo C. and Benet-Buchholz, Jordi and Ballester, Pablo (2008) Quantitative evaluation of anion–π Interactions in solution. Angewandte Chemie International Edition, 47 (22). pp. 4114-4118. ISSN 1433-7851

Full content URL: http://dx.doi.org/10.1002/anie.200800636

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Item Type:Article
Item Status:Live Archive

Abstract

Anions included: A series of meso-tetraaryl calix[4]pyrrole receptors have been used as a model system to quantify chloride–π interactions in solution (see picture; green balls are chloride ions). The free energy values are generally indicative of a repulsive interaction; their magnitude depends on the substituent on the aromatic ring.

Keywords:Chemistry
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:22724
Deposited On:17 Aug 2016 14:44

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