Crystal structures of a calix[4]arene controlled by two affixed pyrene units

Gruber, Tobias and Seichter, Wilhelm and Weber, Edwin (2008) Crystal structures of a calix[4]arene controlled by two affixed pyrene units. Supramolecular Chemistry, 20 (8). pp. 753-760. ISSN 1061-0278

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Item Type:Article
Item Status:Live Archive

Abstract

The synthesis and crystal structures of a calix[4]arene (1) with two affixed pyrene units and its corresponding inclusion compound with chloroform (1a) are reported. In both cases, stacking structures resulting from the influencing control of the pyrene units are observed. The occurrence of infinite or dimeric stack motifs of the pyrene units is dependent on the absence or presence of the included guest solvent.

Keywords:pyrene, Organic synthesis, X-ray diffraction, Molecular Conformation
Subjects:F Physical Sciences > F131 Crystallography
F Physical Sciences > F200 Materials Science
F Physical Sciences > F160 Organic Chemistry
F Physical Sciences > F130 Structural Chemistry
Divisions:College of Science > School of Pharmacy
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ID Code:20030
Deposited On:14 Jan 2016 22:06

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