Crystal structures and isometricity comparison of methylated bisphenol F derivatives

Gruber, Tobias and Nestler, Robert and Seichter, Wilhelm and Bombicz, Petra (2014) Crystal structures and isometricity comparison of methylated bisphenol F derivatives. Journal of Molecular Structure, 1056-7 . pp. 319-325. ISSN 0022-2860

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Crystal structures and isometricity comparison of methylated bisphenol F derivatives

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Abstract

The syntheses and X-ray structures of three methylated bisphenol F derivatives and one respective analogue are reported. A special emphasis lies on the influence of methyl groups on the conformation of the common diphenylmethane scaffold. The introduction of four methyl groups to bisphenol F was found not to disturb its typical strong hydrogen bond network, and yet, to change the pattern of the aromatic interactions in the overall packing. According to the isometricity comparison, the addition of methyl groups to the diphenylmethane core has a greater influence on the conformation of the individual molecules, than the presence or absence of hydrogen bonding donors or acceptors.

Keywords:bisphenol, X-ray study, isometricity comparison, NotOAChecked
Subjects:B Subjects allied to Medicine > B230 Pharmacy
F Physical Sciences > F131 Crystallography
F Physical Sciences > F160 Organic Chemistry
F Physical Sciences > F130 Structural Chemistry
Divisions:College of Science > School of Pharmacy
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ID Code:19714
Deposited On:02 Dec 2015 15:42

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