Organometallic catalysis for applications in radical chemistry and asymmetric synthesis

Aubert, C. and Barbazanges, M. and Jutand, A. and Kyne, S. H. and Ollivier, C. and Fensterbank, L. (2014) Organometallic catalysis for applications in radical chemistry and asymmetric synthesis. Pure and Applied Chemistry, 86 (3). pp. 273-281. ISSN 0033-4545

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Abstract

Two organometallic catalysis studies are presented. The first one deals with the development of a new catalytic agent based on the mixture of a hydride and an iron salt to trigger efficient radical cyclization processes. In a second line of research, we have shown that the use of chiral anions can outperform chiral ligands in a carbocyclization reaction and a 2 + 2 + 2 cycloaddition.

Keywords:Catalysis, Chirality, Electrochemistry, Hydrides, Iron, Ligands, Organometallics, Homogeneous catalysis, NotOAChecked
Subjects:F Physical Sciences > F161 Organometallic Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:17611
Deposited On:08 Jun 2015 15:28

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