Melamine structures on the Au(111) surface

Silly, Fabien and Shaw, Adam Q. and Castell, Martin R. and Briggs, G. A. D. and Mura, Manuela and Martsinovich, Natalia and Kantorovich, Lev (2008) Melamine structures on the Au(111) surface. Journal of Physical Chemistry C, 112 (30). pp. 11476-11480. ISSN 1932-7447

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Item Type:Article
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Abstract

We report on a joint experimental and theoretical study of the ordered structures of melamine molecules formed on the Au(111)-(22 � �3) surface. Scanning tunneling microscopy (STM) images taken under UHV conditions reveal two distinct monolayers one of which has never been reported before on gold. We also find that one of the structures may serve as a transition region ("domain wall") between islands formed by the other arrangement. Using state-of-the-art density functional calculations in conjunction with a systematic gas-phase analysis based on considering all planar structures melamine molecules can form with each other, we propose atomistic models for both structures and the transition region. © 2008 American Chemical Society.

Keywords:Gold, Microscopic examination, Probability density function, Scanning tunneling microscopy, Atomistic modelling, Au (1 1 1), Density-functional calculations, Domain walls, Gas-phase analysis, Melamine structures, Ordered structures, Planar structures, Scanning tunneling microscopy (STM), Transition region, Imaging techniques
Subjects:F Physical Sciences > F320 Chemical Physics
Divisions:College of Science > School of Mathematics and Physics
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http://purl.org/dc/terms/isPartOfhttp://eprints.lincoln.ac.uk/18680/
ID Code:16696
Deposited On:12 Feb 2015 20:00

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