Metabolites of the higher fungi. Part 32. Rosnecatrone, a phytotoxic bicyclo[4.1.0]hept-3-en-2-one from the fungus Rosellinia necatrix Prill

Edwards, Raymond L. and Maitland, Derek J. and Scowen, Ian J. and De Sousa, Antonio J. T. and Whalley, Anthony J. S. (2001) Metabolites of the higher fungi. Part 32. Rosnecatrone, a phytotoxic bicyclo[4.1.0]hept-3-en-2-one from the fungus Rosellinia necatrix Prill. Journal of the Chemical Society, Perkin Transactions 1 (5). pp. 537-542. ISSN UNSPECIFIED

Full content URL: http://dx.doi.org/10.1039/B008195G

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Item Type:Article
Item Status:Live Archive

Abstract

Rosnecatrone 7 is a phytotoxic metabolite isolated from cultures of a virulent strain of the fungus Rosellinia necatrix. The compound is identified as 5-hydroxy-4-hydroxymethyl-1-(1-hydroxy-3-methylbut-2-enyl)-3-(E )-propenyl-7-oxabicyclo4.1.0hept-3-en-2-one by chemical and physical methods. The absolute configuration is determined and the X-ray structure of its borohydride reduced derivative{,} rosnecatrol 10 as the tetra-acetate is described.

Additional Information:First published online 08 Feb 2001 Perkin Transactions 1 ceased publication in 2002. Organic & Biomolecular Chemistry is the RSC's journal for high-quality, original organic chemistry research
Keywords:Chemistry
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
ID Code:13270
Deposited On:19 Mar 2014 19:31

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