Dalton communications. Partial hydrolysis of a Schiff-base tripodal ligand induced by copper(II) salts: crystal structure of the product from reaction with copper(II) perchlorate

Fenton, David E. and Westwood, Gary P. and Bashall, Alan and McPartlin, Mary and Scowen, Ian J. (1994) Dalton communications. Partial hydrolysis of a Schiff-base tripodal ligand induced by copper(II) salts: crystal structure of the product from reaction with copper(II) perchlorate. Journal of the Chemical Society, Dalton Trans. (14). pp. 2213-2214. ISSN 1477-9226

Full content URL: http://dx.doi.org/10.1039/DT9940002213

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Item Type:Article
Item Status:Live Archive

Abstract

The reaction of Cu(ClO) or Cu(NO) with a potentially heptadentate Schiff-base tripod derived from tris(2-aminoethyl)amine and 2-hydroxyacetophenone occurs with accompanying hydrolysis of the ligand; single-crystal X-ray structure analysis of the product involving Cu(ClO) shows the ligand to exist in a zwitterionic form and provide a near square-planar environment for the copper() cation.

Keywords:Chemistry
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
ID Code:13255
Deposited On:19 Mar 2014 17:55

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