Two tetrathiafulvalene salts of a new thiophene-functionalised ferracarborane: electrical conductivity as a function of crystal composition

Yan, Yaw-Kai and Mingos, D. Michael P. and Kurmoo, Mohamedally and Li, Wan-Sheung and Scowen, Ian J. and McPartlin, Mary and Coomber, A. Treeve and Friend, Richard H. (1995) Two tetrathiafulvalene salts of a new thiophene-functionalised ferracarborane: electrical conductivity as a function of crystal composition. Journal of the Chemical Society, Chemical Communications (10). pp. 997-998. ISSN 0022-4936

Full content URL: http://dx.doi.org/10.1039/C39950000997

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Item Type:Article
Item Status:Live Archive

Abstract

Two tetrathiafulvalenium (TTF) salts of the new sandwich complex commo-3{,}3prime or minute]-Fe1-(thiophene-2-yl)-1,2-CBH], TTFFe(CBHCHS) and TTFFe(CBHCHS){,} are synthesized; while the 1 : 1 salt is an insulator{,} the 5 : 2 salt is a semiconductor featuring a conducting superlattice associated with a sublattice that shows ferromagnetic interactions between the ferracarborane complexes; single crystal X-ray studies of the 5 : 2 salt indicate that the electrical conductivity originates from a unique mixed-valence TTF network.

Additional Information:Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995
Keywords:Chemistry
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
ID Code:13254
Deposited On:19 Mar 2014 19:31

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