Partial hydrolysis of a Schiff-base tripodal ligand induced by copper(II) salts: crystal structure of the product from reaction with copper(II) perchlorate

Fenton, D. E. and Westwood, G. P. and Bashall, A. and McPartlin, M. and Scowen, I. J. (1994) Partial hydrolysis of a Schiff-base tripodal ligand induced by copper(II) salts: crystal structure of the product from reaction with copper(II) perchlorate. Journal of the Chemical Society, Dalton Transactions (14). pp. 2213-2214. ISSN 1472-7773

Full content URL: http://dx.doi.org/10.1039/DT9940002213

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Item Type:Article
Item Status:Live Archive

Abstract

The reaction of Cu(ClO4)2 or Cu(NO3)2 with a potentially heptadentate Schiff-base tripod derived from tris(2-aminoethyl)amine and 2-hydroxyacetophenone occurs with accompanying hydrolysis of the ligand; single-crystal X-ray structure analysis of the product involving Cu(ClO4)2 shows the ligand to exist in a zwitterionic form and provide a near square-planar environment for the copper(II) cation.

Keywords:Crystal structure
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13117
Deposited On:19 Mar 2014 19:50

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