Ambidentate binding in macrocyclic helicates: towards tuning secondary structure

Matthews, Ray W. and McPartlin, Mary and Scowen, Ian J. (1996) Ambidentate binding in macrocyclic helicates: towards tuning secondary structure. Chemical Communications (3). pp. 309-310. ISSN 13597345

Full content URL: http://dx.doi.org/10.1039/CC9960000309

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Item Type:Article
Item Status:Live Archive

Abstract

X-Ray analysis of new helicates of CdII and PbII derived from a tetraimine macrocyclic ligand shows that the compression of the double-helical array as the size of the metal ion increases corresponds with a change in coordination mode of the ligand.

Keywords:Chemistry
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13098
Deposited On:19 Mar 2014 19:42

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