Aggregation of tripodal thallium(I) amides through weak TlI-TlI interactions

Hellmann, Konrad W. and Gade, Lutz H. and Scowen, Ian J. and McPartlin, Mary (1996) Aggregation of tripodal thallium(I) amides through weak TlI-TlI interactions. Chemical Communications, 1996 (22). pp. 2515-2516. ISSN 1359-7345

Full content URL: http://dx.doi.org/10.1039/CC9960002515

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Item Type:Article
Item Status:Live Archive

Abstract

Metal exchange between the lithium amide MeSiSiMe2N-(Li)But3 and TlCl yields the corresponding thallium amide MeSiSiMe2N(Tl)But3 1 which aggregates in the solid through weak attractive Tl�Tl interactions to form infinite molecular chains; competing redox chemistry leads to the dimetallated species HCSiMe2N(Tl)But2SiMe2NHBu t 2 in the analogous metal-exchange process involving the trisilylmethane derivative.

Keywords:Metal exchange
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13096
Deposited On:19 Mar 2014 19:43

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